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Validation of Diethoxyphosphonate as an Effective Agent for Charge Transfer in Anion Relay Chemistry (ARC)

[Image: see text] The diethoxyphosphonate group comprises an effective agent to achieve negative charge migration in Type II Anion Relay Chemistry (ARC). The process involves a [1,4]-phosphorus-Brook rearrangement that proceeds via a phosphacyclic intermediate leading to an anion that can be capture...

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Main Authors: Sokolsky, Alexander, Smith, Amos B.
Formato: Artigo
Idioma:Inglês
Publicado: 2012
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3439805/
https://ncbi.nlm.nih.gov/pubmed/22880799
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3019709
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