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Radical reactions of thiamin pyrophosphate in 2-oxoacid oxidoreductases()
Thiamin pyrophosphate (TPP) is essential in carbohydrate metabolism in all forms of life. TPP-dependent decarboxylation reactions of 2-oxo-acid substrates result in enamine adducts between the thiazolium moiety of the coenzyme and decarboxylated substrate. These central enamine intermediates experie...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3438339/ https://ncbi.nlm.nih.gov/pubmed/22178227 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bbapap.2011.11.010 |
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