Mechanism of the mutagenic action of hydroxylamine. IX. The UV-induced cleavage of the N-O bond in N4-hydroxy-and N4-methoxycytidine and N6-methoxyadenosine.

The principal UV-induced (lambda = 2546nm) reaction of N4-hydroxy- and N4methoxycytidines and N6-methoxyadenosine in neutral aqueous solutions is cleavage of the exocyclic N-O bond with the respective formation of cytidine and adenosine. Quantum yields are 2.8x10(-3) and 2.2x10(-3) M/E for the first...

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Bibliographic Details
Main Authors: Simukova, N A, Yakovlev, D Y, Budowsky, E I
Format: Artigo
Language:Inglês
Published: 1975
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC343594/
https://ncbi.nlm.nih.gov/pubmed/1052542
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