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Di-μ-chlorido-μ-(dimethyl sulfide)-bis{dichlorido[(dimethyl selenide-κSe)(dimethyl sulfide-κS)(0.65/0.35)]niobium(III)}(Nb—Nb)
The dinuclear compound, [Nb(2)Cl(6)(C(2)H(6)S)(1.7)(C(2)H(6)Se)(1.3)], features an Nb(III)=Nb(III) double bond [2.6878 (5) Å]. The molecule lies on a twofold rotation axis that passes through the middle of this bond as well as through the bridging dimethyl sulfide ligand. The Nb(III) ion exists in...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
International Union of Crystallography
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3435590/ https://ncbi.nlm.nih.gov/pubmed/22969463 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536812033673 |
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