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Pulse Q-Band EPR and ENDOR Spectroscopies of the Photochemically Generated Monoprotonated Benzosemiquinone Radical in Frozen Alcoholic Solution

Quinones are essential cofactors in many physiological processes, among them proton-coupled electron transfer (PCET) in photosynthesis and respiration. A key intermediate in PCET is the monoprotonated semiquinone radical. In this work we produced the monoprotonated benzosemiquinone (BQH(•)) by UV il...

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Hlavní autoři: Flores, Marco, Okamura, Melvin Y., Niklas, Jens, Pandelia, Maria-Eirini, Lubitz, Wolfgang
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3432317/
https://ncbi.nlm.nih.gov/pubmed/22731760
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp304555u
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