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Competing pathways in the photo-Favorskii rearrangement and release of esters: Studies on fluorinated p-hydroxyphenacyl GABA and glutamate phototriggers

Three new trifluoromethylated p-hydroxyphenacyl (pHP) caged γ-aminobutyric acid (GABA) and glutamate (Glu) derivatives have been examined for their efficacy as photoremovable protecting groups in aqueous solution. By replacing hydrogen with fluorine, e.g., a m-trifluoromethyl or a m-trifluoromethoxy...

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Main Authors: Stensrud, Kenneth, Noh, Jihyun, Kandler, Karl, Wirz, Jakob, Heger, Dominik, Givens, Richard S.
Formato: Artigo
Idioma:Inglês
Publicado: 2009
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3422889/
https://ncbi.nlm.nih.gov/pubmed/19572582
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900139h
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