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2-Hydroxyphenacyl ester: A new photoremovable protecting group

2-Hydroxyphenacyl moiety absorbing below 370 nm is proposed as a new photoremovable protecting group for carboxylates and sulfonates. Laser flash photolysis and steady-state sensitization studies showed that the leaving group is released from a short-lived triplet state. In addition, DFT-based quant...

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Detalhes bibliográficos
Main Authors: Ngoy, Bokolombe Pitchou, Šebej, Peter, Šolomek, Tomáš, Lim, Bum Hee, Pastierik, Tomáš, Park, Bong Ser, Givens, Richard S., Heger, Dominik, Klán, Petr
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3422872/
https://ncbi.nlm.nih.gov/pubmed/22766787
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2pp25133g
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