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Identification of Heme Propionate Vibrational Modes in the Resonance Raman Spectra of Cytochrome c Oxidase

The propionate groups of heme a and a(3) in cytochrome c oxidase (CcO), have been postulated to mediate both the electron and proton transfer within the enzyme. To establish structural markers for the propionate groups, their associated vibrational modes were identified in the resonance Raman spectr...

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Bibliographic Details
Main Authors: Egawa, Tsuyoshi, Lee, Hyun Ju, Ji, Hong, Gennis, Robert B., Yeh, Syun-Ru, Rousseau, Denis L.
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3418657/
https://ncbi.nlm.nih.gov/pubmed/19563766
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ab.2009.06.035
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