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Electrocatalytic mechanism of reversible hydrogen cycling by enzymes and distinctions between the major classes of hydrogenases

The extraordinary ability of Fe- and Ni-containing enzymes to catalyze rapid and efficient H(+)/H(2) interconversion—a property otherwise exclusive to platinum metals—has been investigated in a series of experiments combining variable-temperature protein film voltammetry with mathematical modeling....

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Detalhes bibliográficos
Main Authors: Hexter, Suzannah V., Grey, Felix, Happe, Thomas, Climent, Victor, Armstrong, Fraser A.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3406873/
https://ncbi.nlm.nih.gov/pubmed/22802675
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1204770109
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