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Concise Total Synthesis of (+)-Gliocladins B and C

The first total synthesis of (+)-gliocladin B is described. Our concise and enantioselective synthesis takes advantage of a new regioselective Friedel–Crafts-based strategy to provide an efficient multigram-scale access to the C3-(3′-indolyl)hexahydropyrroloindole substructure, a molecular foundatio...

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Detalles Bibliográficos
Main Authors: Boyer, Nicolas, Movassaghi, Mohammad
Formato: Artigo
Idioma:Inglês
Publicado: 2012
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3404843/
https://ncbi.nlm.nih.gov/pubmed/22844577
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC20270K
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