Spectroscopic Studies of Bridge Contributions to Electronic Coupling in a Donor-Bridge-Acceptor Biradical System

Variable temperature electronic absorption and resonance Raman spectroscopies are used to probe the excited state electronic structure of Tp(Cum,Me)Zn(SQ-Ph-NN) (1) – a donor-bridge-acceptor (D-B-A) biradical complex and a ground state analog of the charge-separated excited state formed in photoindu...

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Bibliographic Details
Main Authors: Kirk, Martin L., Shultz, David A., Depperman, Ezra C., Habel-Rodriguez, Diana, Schmidt, Robert D.
Format: Artigo
Language:Inglês
Published: 2012
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3398980/
https://ncbi.nlm.nih.gov/pubmed/22480156
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja300233a
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