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Rh(2)(II)-Catalyzed Intramolecular Aliphatic C–H Bond Amination Reactions Using Aryl Azides as the N-Atom Source

Rhodium(II) dicarboxylate complexes were discovered to catalyze the intramolecular amination of unactivated primary-, secondary-, or tertiary aliphatic C–H bonds using aryl azides as the N-atom precursor. While a strong electron-withdrawing group on the nitrogen atom is typically required to achieve...

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Detalhes bibliográficos
Main Authors: Nguyen, Quyen, Sun, Ke, Driver, Tom G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3397916/
https://ncbi.nlm.nih.gov/pubmed/22519742
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja301519q
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