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An olefin metathesis-iodoetherification-dehydroiodination strategy for spiroketal subunits of the polyether antibiotics

[Image: see text] The convergent synthesis of two pentacyclic analogs of the polyether monensin A is described. Although different with respect to the configuration of the alcohol at the 3 position of the six membered ring of the spiroketal subunit, the configuration at the acetal center in both str...

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Detalhes bibliográficos
Main Authors: Tony, Kurissery A., Dabideen, Darrin, Li, Jialiang, Díaz-Hernández, Maria Dolores, Jiménez-Barbero, Jesús, Mootoo, David R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3395214/
https://ncbi.nlm.nih.gov/pubmed/19813766
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo9014722
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