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Direct evidence of active site reduction and photo-driven catalysis in sensitized hydrogenase assemblies

We report photo-catalytic H(2) production by hydrogenase (H(2)ase)-quantum dot (QD) hybrid assemblies. Quenching of the CdTe exciton emission is observed, consistent with electron transfer from quantum dot to H(2)ase. GC analysis shows light driven H(2) production in the presence of a sacrificial el...

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Detalhes bibliográficos
Main Authors: Greene, Brandon L., Joseph, Crisjoe A., Maroney, Michael J., Dyer, R. Brian
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3394927/
https://ncbi.nlm.nih.gov/pubmed/22716776
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3042367
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