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Phosphine/Palladium-Catalyzed Syntheses of Alkylidene Phthalans, 3-Deoxyisoochracinic Acid, Isoochracinic Acid, and Isoochracinol
[Image: see text] In this study we used sequential-catalysis—PPh(3)-catalyzed nucleophilic addition followed by Pd(0)-catalyzed Heck cyclization—to construct complex functionalized alkylidene phthalans rapidly, in high yields, and with good stereoselectivities (E:Z ratios of up to 1:22). The scope o...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3391320/ https://ncbi.nlm.nih.gov/pubmed/22721256 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol301154f |
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