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Benzylation of Nitroalkanes Using Copper-Catalyzed Thermal Redox Catalysis: Toward the Facile C-Alkylation of Nitroalkanes

The C-alkylation of nitroalkanes under mild conditions has been a significant challenge in organic synthesis for more than a century. Herein, we report a simple Cu(I) catalyst, generated in situ, that is highly effective for C-benzylation of nitroalkanes using abundant benzyl bromides and related he...

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Hlavní autoři: Gildner, Peter G., Gietter, Amber A. S., Cui, Di, Watson, Donald A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3389751/
https://ncbi.nlm.nih.gov/pubmed/22691127
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja304561c
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