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Electron Paramagnetic Resonance Characterization of Tetrahydrobiopterin Radical Formation in Bacterial Nitric Oxide Synthase Compared to Mammalian Nitric Oxide Synthase

H(4)B is an essential catalytic cofactor of the mNOSs. It acts as an electron donor and activates the ferrous heme-oxygen complex intermediate during Arg oxidation (first step) and NOHA oxidation (second step) leading to nitric oxide and citrulline as final products. However, its role as a proton do...

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Detalhes bibliográficos
Main Authors: Brunel, Albane, Santolini, Jérôme, Dorlet, Pierre
Formato: Artigo
Idioma:Inglês
Publicado em: The Biophysical Society 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3388219/
https://ncbi.nlm.nih.gov/pubmed/22828337
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bpj.2012.05.032
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