Multiconfigurational nature of 5f orbitals in uranium and plutonium intermetallics

Uranium and plutonium’s 5f electrons are tenuously poised between strongly bonding with ligand spd-states and residing close to the nucleus. The unusual properties of these elements and their compounds (e.g., the six different allotropes of elemental plutonium) are widely believed to depend on the r...

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Autori principali: Booth, C.H., Jiang, Yu, Wang, D.L., Mitchell, J.N., Tobash, P.H., Bauer, E.D., Wall, M.A., Allen, P.G., Sokaras, D., Nordlund, D., Weng, T.-C., Torrez, M.A., Sarrao, J.L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2012
Soggetti:
Physical Sciences
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3387120/
https://ncbi.nlm.nih.gov/pubmed/22706643
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1200725109
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