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Anions dramatically enhance proton transfer through aqueous interfaces

Proton transfer (PT) through and across aqueous interfaces is a fundamental process in chemistry and biology. Notwithstanding its importance, it is not generally realized that interfacial PT is quite different from conventional PT in bulk water. Here we show that, in contrast with the behavior of st...

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Bibliografske podrobnosti
Main Authors: Mishra, Himanshu, Enami, Shinichi, Nielsen, Robert J., Hoffmann, Michael R., Goddard, William A., Colussi, Agustín J.
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 2012
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3387034/
https://ncbi.nlm.nih.gov/pubmed/22689964
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1200949109
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