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Anti-Arrhenius cleavage of covalent bonds in bottlebrush macromolecules on substrate
Spontaneous degradation of bottlebrush macromolecules on aqueous substrates was monitored by atomic force microscopy. Scission of C─C covalent bonds in the brush backbone occurred due to steric repulsion between the adsorbed side chains, which generated bond tension on the order of several nano-Newt...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3386079/ https://ncbi.nlm.nih.gov/pubmed/22645366 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1118517109 |
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