Metalloenzyme-like catalyzed isomerizations of sugars by Lewis acid zeolites

Isomerization of sugars is used in a variety of industrially relevant processes and in glycolysis. Here, we show that hydrophobic zeolite beta with framework tin or titanium Lewis acid centers isomerizes sugars, e.g., glucose, via reaction pathways that are analogous to those of metalloenzymes. Spec...

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Bibliographic Details
Main Authors: Bermejo-Deval, Ricardo, Assary, Rajeev S., Nikolla, Eranda, Moliner, Manuel, Román-Leshkov, Yuriy, Hwang, Son-Jong, Palsdottir, Arna, Silverman, Dorothy, Lobo, Raul F., Curtiss, Larry A., Davis, Mark E.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2012
Subjects:
Physical Sciences
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3382492/
https://ncbi.nlm.nih.gov/pubmed/22665778
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1206708109
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