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Nucleophilic Participation in the Solvolyses of (Arylthio)methyl Chlorides and Derivatives: Application of Simple and Extended Forms of the Grunwald-Winstein Equations

The specific rates of solvolysis of chloromethyl phenyl sulfide [(phenylthio)methyl chloride] and its p-chloro-derivative have been determined at 0.0 °C in a wide range of hydroxylic solvents, including several containing a fluroalcohol. Treatment in terms of a two-term Grunwald-Winstein equation, i...

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Autors principals: Kevill, Dennis N., Park, Young Hoon, Park, Byoung-Chun, D’Souza, Malcolm J.
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3375722/
https://ncbi.nlm.nih.gov/pubmed/22711999
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.2174/138527212800672592
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