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Origins of Enantioselectivity during Allylic Substitution Reactions Catalyzed by Metallacyclic Iridium Complexes

In depth mechanistic studies of iridium catalyzed regioselective and enantioselective allylic substitution reactions are presented. A series of cyclometallated allyliridium complexes that are kinetically and chemically competent to be intermediates in the allylic substitution reactions was prepared...

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Bibliografiske detaljer
Main Authors: Madrahimov, Sherzod T., Hartwig, John F.
Format: Artigo
Sprog:Inglês
Udgivet: 2012
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3368983/
https://ncbi.nlm.nih.gov/pubmed/22486270
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja212217j
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