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Total Synthesis of the Potent cAMP Signaling Agonist (−)-Alotaketal A
We developed a convergent synthetic route to the potent cAMP signaling agonist (−)-alotaketal A employing two stages of SmI(2)-mediated reductive allylation reactions for assembling the polycycle and fragment coupling. Also notable are a Hg(OAc)(2)-mediated selective alkene oxidation and the subtlet...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3365617/ https://ncbi.nlm.nih.gov/pubmed/22563931 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303529z |
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