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Diffusion frequency factors in some simple examples of transition-state rate theory.
In the Eyring rate theory, the rate constant is expressed as a product of a frequency factor (kT/h) and a quotient of partition functions. Continuing an earlier paper, it is shown here by means of simple examples that the Eyring formalism may be extended to include diffusion-controlled processes if...
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
1976
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC335981/ https://ncbi.nlm.nih.gov/pubmed/1062777 |
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