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Isotope Effects and Heavy-Atom Tunneling in the Roush Allylboration of Aldehydes
[Image: see text] Intermolecular (13)C kinetic isotope effects (KIEs) for the Roush allylboration of p-anisaldehyde were determined using a novel approach. The experimental (13)C KIEs fit qualitatively with the expected rate-limiting cyclic transition state, but they are far higher than theoretical...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3345075/ https://ncbi.nlm.nih.gov/pubmed/22506639 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300789a |
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