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Lithium cation enhances anion binding in a tripodal phosphine oxide-based ditopic receptor
A tripodal ditopic receptor presents H-bond donors and a phosphine oxide to potential guests. In the idealized binding conformation, an endohedral P═O functionality provides enhanced halide binding in the presence of lithium with the greatest ΔΔG° observed for bromide, while minimal changes in K(a)...
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| Autori principali: | , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3344749/ https://ncbi.nlm.nih.gov/pubmed/21655566 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c1cc12475g |
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