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Site-Selective Catalysis: towards a regiodivergent resolution of 1,2-diols
This paper demonstrates that the secondary hydroxyl can be functionalized in preference to the primary hydroxyl of a 1,2-diol. The site selectivity is achieved by using an enantioselective organic catalyst that is able to reversibly and covalently bond to the diol. The reaction was parlayed into a d...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3342470/ https://ncbi.nlm.nih.gov/pubmed/22515351 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3027086 |
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