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Alkenenitrile Transmissive Olefination: Synthesis of the Putative Lignan "Morinol I"
Grignard reagents trigger an addition-elimination with α'-hydroxy acrylonitriles to selectively generate Z-alkenenitriles. The modular assembly of Z-alkenenitriles from a Grignard reagent, acrylonitrile, and an aldehyde is ideal for stereoselectively synthesizing alkenes as illustrated in the s...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3336159/ https://ncbi.nlm.nih.gov/pubmed/22545004 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201101235 |
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