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Theory of volume transition in polyelectrolyte gels with charge regularization
We present a theory for polyelectrolyte gels that allow the effective charge of the polymer backbone to self-regulate. Using a variational approach, we obtain an expression for the free energy of gels that accounts for the gel elasticity, free energy of mixing, counterion adsorption, local dielectri...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Institute of Physics
2012
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3331872/ https://ncbi.nlm.nih.gov/pubmed/22482584 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.3698168 |
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