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Theory of volume transition in polyelectrolyte gels with charge regularization

We present a theory for polyelectrolyte gels that allow the effective charge of the polymer backbone to self-regulate. Using a variational approach, we obtain an expression for the free energy of gels that accounts for the gel elasticity, free energy of mixing, counterion adsorption, local dielectri...

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Detalhes bibliográficos
Main Authors: Hua, Jing, Mitra, Mithun K., Muthukumar, M.
Formato: Artigo
Idioma:Inglês
Publicado em: American Institute of Physics 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3331872/
https://ncbi.nlm.nih.gov/pubmed/22482584
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.3698168
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