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Diels–Alder reaction of maldoxin with an isopropenylallene

The Diels–Alder reaction of maldoxin with an isopropenylallene at 60-75 °C afforded an adduct closely related to chloropestolide A (24%) and a second adduct (0-11%) that underwent an ene reaction to generate the chloropupukeanolide D (11-22%) skeleton. The Diels–Alder reaction occurred with good sel...

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Detalhes bibliográficos
Main Authors: Yu, Min, Snider, Barry. B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3327307/
https://ncbi.nlm.nih.gov/pubmed/22518065
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.09.117
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