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Rhodium(I)/Diene-Catalyzed Addition Reactions of Arylborons with Ketones

[Image: see text] Rh(I)/diene-catalyzed addition reactions of arylboroxines/arylboronic acids with unactivated ketones to form tertiary alcohols in good to excellent yields are described. By using C(2)-symmetric (3aR,6aR)-3,6-diaryl-1,3a,4,6a-tetrahydropentalenes as ligands, the asymmetric version o...

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Bibliographic Details
Main Authors: Liao, Yuan-Xi, Xing, Chun-Hui, Hu, Qiao-Sheng
Format: Artigo
Language:Inglês
Published: 2012
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3312017/
https://ncbi.nlm.nih.gov/pubmed/22376059
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300275s
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