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Synthesis of oleophilic electron-rich phenylhydrazines

Phenylhydrazines 1 substituted with two or three long-chain alkyl, alkoxy or alkylsulfanyl groups were successfully prepared by acid-induced removal of the Boc group in hydrazides 2. The reaction is carried out with 5 equivalents of TfOH in CF(3)CH(2)OH/CH(2)Cl(2) at −40 °C for 1.5 min. Under these...

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Bibliografiska uppgifter
Huvudupphovsmän: Jankowiak, Aleksandra, Kaszyński, Piotr
Materialtyp: Artigo
Språk:Inglês
Publicerad: Beilstein-Institut 2012
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC3302090/
https://ncbi.nlm.nih.gov/pubmed/22423295
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.29
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