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A ferrocene redox-active triazolium macrocycle that binds and senses chloride

A ferrocene bis(triazole) macrocycle was synthesised in good yield by the Eglinton coupling of an acyclic bis(alkyne) precursor and characterised in the solid state by X-ray crystallography. Alkylation gives the corresponding triazolium macrocycle, which binds chloride and benzoate strongly in CD(3)...

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Detalhes bibliográficos
Main Authors: White, Nicholas G, Beer, Paul D
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3302085/
https://ncbi.nlm.nih.gov/pubmed/22423291
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.25
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