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Synthetic Studies Directed Toward Dideoxy Lomaiviticinone lead to Unexpected 1,2-Oxazepine and Isoxazole Formation
[Image: see text] In the course of studies directed toward the synthesis of dideoxy lomaiviticinone, 3-(nitromethyl)cyclohexenones 2a (X = H) and 2b (X =I) were prepared. The corresponding enolates were reacted with naphthazarin (1) and unexpectedly afforded 1,2-oxazepine 3 and isoxazole 4, respecti...
সংরক্ষণ করুন:
| প্রধান লেখক: | , |
|---|---|
| বিন্যাস: | Artigo |
| ভাষা: | Inglês |
| প্রকাশিত: |
2012
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| বিষয়গুলি: | |
| অনলাইন ব্যবহার করুন: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3292050/ https://ncbi.nlm.nih.gov/pubmed/22309201 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol203390w |
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