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Transient Ru-methyl formate intermediates generated with bifunctional transfer hydrogenation catalysts

Desorption electrospray ionization (DESI) coupled to high-resolution Orbitrap mass spectrometry (MS) was used to study the reactivity of a (β-amino alcohol)(arene)RuCl transfer hydrogenation catalytic precursor in methanol (CH(3)OH). By placing [(p-cymene)RuCl(2)](2) on a surface and spraying a solu...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Perry, Richard H., Brownell, Kristen R., Chingin, Konstantin, Cahill, Thomas J., Waymouth, Robert M., Zare, Richard N.
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 2012
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3289342/
https://ncbi.nlm.nih.gov/pubmed/22315417
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1118934109
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