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Photocatalytic [2+2] Cycloadditions of Enones with Cleavable Redox Auxiliaries

[Image: see text] α,β-Unsaturated 2-imidazolyl ketones undergo [2+2] cycloaddition with a variety of Michael acceptors upon irradiation with visible light in the presence of Ru(bpy)(3)(2+). Cleavage of the imidazolyl auxiliary from the cycloadducts affords cyclobutane carboxamides, esters, thioester...

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Detalhes bibliográficos
Main Authors: Tyson, Elizabeth L., Farney, Elliot P., Yoon, Tehshik P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3288794/
https://ncbi.nlm.nih.gov/pubmed/22320352
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3000298
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