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Cis-Selective Ring-Opening Metathesis Polymerization with Ruthenium Catalysts

Using a C-H activated, ruthenium-based metathesis catalyst, the cis selective ROMP of several monocyclic alkenes, as well as norbornene and oxanorbornene-type monomers is reported. The cis content of the isolated polymers depended heavily on monomer structure and temperature. By lowering the tempera...

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Autori principali: Keitz, Benjamin K., Fedorov, Alexey, Grubbs, Robert H.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2012
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3278323/
https://ncbi.nlm.nih.gov/pubmed/22239675
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211676y
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