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Enthalpy vs Entropy Driven Complexation of Homoallylic Alcohols by Rh(I) Complexes
The thermodynamics of binding between several homoallylic alcohols and simple olefinic Rh(I) compounds was examined with (1)H NMR spectroscopy and ITC. (1)H NMR titrations revealed moderate binding of these alcohols with [Rh(COD)(2)](+) (1) and [Rh(COD)(CH(3)CN)(2)](+) (3), but weaker binding with [...
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3274780/ https://ncbi.nlm.nih.gov/pubmed/22328800 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om200793p |
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