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A Study of Mo(4+)Quinoxalyl-Dithiolenes as Models for the Non-Innocent Pyranopterin in the Molybdenum Cofactor
A model system for the molybdenum cofactor has been developed that illustrates the non-innocent behavior of a N-heterocycle appended to a dithiolene chelate on molybdenum. The pyranopterin of the molybdenum cofactor is modeled by a quinoxalyl-dithiolene ligand (S(2)BMOQO) formed from reaction of a m...
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| Autori principali: | , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3268461/ https://ncbi.nlm.nih.gov/pubmed/21894968 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic200783a |
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