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Chiroptical spectra of a series of tetrakis((+)–3–heptafluorobutylyrylcamphorato)lanthanide(III) with an encapsulated alkali metal ion: circularly polarized luminescence and absolute chiral structures for the Eu(III) and Sm(III) complexes
The luminescence and circularly polarized luminescence (CPL) spectra of M(I)[Eu((+)–hfbc)(4)] show a similar behavior to the exciton CD in the intraligand π–π(*) transitions when the alkali metal ions and solvents are manipulated. There is a difference in susceptibility in solvation toward the alkal...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3262478/ https://ncbi.nlm.nih.gov/pubmed/22074461 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic201851r |
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