Protonation of a Neutral (S)-β-Bisabolene Intermediate Is Involved in (S)-β-Macrocarpene Formation by the Maize Sesquiterpene Synthases TPS6 and TPS11

Terpene synthases are responsible for the large diversity of terpene carbon skeletons found in plants. The unique, carbocationic reaction mechanism of these enzymes can form multiple products from a single prenyl diphosphate substrate. Two maize genes were isolated that encode very similar sesquiter...

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Autores principales: Köllner, Tobias G., Schnee, Christiane, Li, Shenghong, Svatoš, Aleš, Schneider, Bernd, Gershenzon, Jonathan, Degenhardt, Jörg
Formato: Artigo
Lenguaje:Inglês
Publicado: American Society for Biochemistry and Molecular Biology 2008
Materias:
Enzyme Catalysis and Regulation
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3258946/
https://ncbi.nlm.nih.gov/pubmed/18524777
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M802682200
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