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Tertiary alcohol preferred: Hydroxylation of trans-3-methyl-L-proline with proline hydroxylases
The enzymatic synthesis of tertiary alcohols by the stereospecific oxidation of tertiary alkyl centers is a most-straightforward but challenging approach, since these positions are sterically hindered. In contrast to P450-monooxygenases, there is little known about the potential of non-heme iron(II)...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Beilstein-Institut
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3252868/ https://ncbi.nlm.nih.gov/pubmed/22238542 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.193 |
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