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μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)

The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl...

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Detalhes bibliográficos
Main Authors: Yin, Bang-Shao, Li, Tian-Bao, Yang, Ming-Sheng
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3246933/
https://ncbi.nlm.nih.gov/pubmed/22219753
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536811040621
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