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Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes
Addition of LiOHMT (OHMT = O-2,6-dimesitylphenoxide) to W(O)(CH-t-Bu)(PMe(2)Ph)(2)Cl(2) led to WO(CH-t-Bu)Cl(OHMT)(PMe(2)Ph) (4). Subsequent addition of Li(2,5-Me(2)C(4)H(2)N) to 4 yielded yellow W(O)(CH-t-Bu)(OHMT)(Me(2)Pyr)(PMe(2)Ph) (5). Compound 5 is a highly effective catalyst for the Z-selecti...
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| Main Authors: | , , , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2011
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3244563/ https://ncbi.nlm.nih.gov/pubmed/22107254 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja210349m |
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