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Synthesis and spectroscopic analysis of a stereoisomer library of the phytophthora mating hormone α1 and derived bis-Mosher esters

Fluorous mixture synthesis provided all eight diastereomers of the phytophthora hormone α1 with the R configuration at C11 as individual samples after demixing and detagging. The library of all possible bis-Mosher esters (16) was then made by esterification. Complete sets of (1)H, (13)C and (for the...

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Main Authors: Bajpai, Reena, Curran, Dennis P.
格式: Artigo
語言:Inglês
出版: 2011
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3241891/
https://ncbi.nlm.nih.gov/pubmed/22047536
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2082679
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