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Enantioselective Conjugate Allylation of Cyclic Enones

[Image: see text] Enantioselective organocatalytic 1,2-allylation of a cyclic enone followed by anionic oxy-Cope rearrangement delivered the ketone as a mixture of diastereomers. This appears to be a general method for the net enantioselective conjugate allylation of cyclic enones.

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Autors principals: Taber, Douglass F., Gerstenhaber, David A., Berry, James F.
Format: Artigo
Idioma:Inglês
Publicat: 2011
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3237403/
https://ncbi.nlm.nih.gov/pubmed/21830779
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo2013753
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