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One-Pot Synthesis of Polyrotaxanes via Acyclic Diene Metathesis Polymerization of Supramolecular Monomers

A one-pot synthesis of polyrotaxanes has been developed. The method employs a supramolecular monomer comprising a polymerizable ammonium salt and crown ether, in combination with dynamic ADMet polymerization. Ultimately, highly efficient complexation, polymerization, and end-capping were accomplishe...

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Détails bibliographiques
Auteurs principaux: Momčilović, Nebojša, Clark, Paul G., Boydston, Andrew J., Grubbs, Robert H.
Format: Artigo
Langue:Inglês
Publié: 2011
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3236677/
https://ncbi.nlm.nih.gov/pubmed/22023086
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja208515r
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