Substrate free radicals are intermediates in ligninase catalysis.

The H2O2-requiring ligninase of the basidiomycete Phanerochaete chrysosporium oxidatively cleaves both lignin and lignin model compounds between C alpha and C beta (C-1 and C-2) of their aliphatic side chains. Previous work has demonstrated a reaction mechanism by which ligninase oxidizes aromatic s...

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Veröffentlicht in:	Proc Natl Acad Sci U S A
Hauptverfasser:	Hammel, K E, Kalyanaraman, B, Kirk, T K
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	National Academy of Sciences 1986
Schlagworte:	Research Article
Online-Zugang:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC323592/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3012530/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.83.11.3708
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