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Controlling the pKa of the bacteriorhodopsin Schiff base by use of artificial retinal analogues.

Artificial bacteriorhodopsin pigments based on synthetic retinal analogues carrying an electron-withdrawing CF3 substituent group were prepared. The effects of CF3 on the spectra, photocycles, and Schiff base pKa values of the pigments were analyzed. A reduction of 5 units in the pKa of the Schiff b...

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Dettagli Bibliografici
Autori principali: Sheves, M, Albeck, A, Friedman, N, Ottolenghi, M
Natura: Artigo
Lingua:Inglês
Pubblicazione: 1986
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC323493/
https://ncbi.nlm.nih.gov/pubmed/3458179
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